GENIUM PUBLISHING CORP -- IRON WIRE -- 6810-00N052183
===================== Product Identification ===================== Product ID:IRON WIRE MSDS Date:07/01/1991 FSC:6810 NIIN:00N052183 === Responsible Party === Company Name:GENIUM PUBLISHING CORP Address:1145 CATALYN ST City:SCHENECTADY State:NY ZIP:12303-1836 Country:US Info Phone Num:518-377-8854 Emergency Phone Num:518-377-8854 Preparer's Name:M. GANNON CAGE:5Z768 === Contractor Identification === Company Name:GENIUM PUBLISHING CORPORATION Address:1145 CATALYN ST Box:City:SCHENECTADY State:NY ZIP:12303-1836 Country:US Phone:518-377-8854 CAGE:5Z768 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 91-99% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3 FUME (FE) Ingred Name:SUPP DATA:TO SEWERS OR WATERWAYS. RTECS #:9999999ZZ Ingred Name:EXPLO HAZ:REMOVE DUST DURING GRINDING & POLISHING OPERATIONS. RTECS #:9999999ZZ Ingred Name:CNDTNS(STAB):AIR. AVOID GENERATION OF IRON DUSTS & CONTACT W/MATERIALS LISTED. RTECS #:9999999ZZ Ingred Name:MATLS TO AVOID:ACID, AMMONIUM NITRATE, HALOGENS, DINITROGEN TETRAOXIDE, NITRYL FLUORIDE, POLYSTYRENE, SODIUM (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:ACETYLIDE, POTASSIUM DICHROMATE, PEROXYFORMIC ACID & NITRYL FLUORIDE. HOT IRON WIRE BURNS IN CHLORINE GAS (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:& IRON W/WATER FORMS RUST. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:HAS OCCURRED W/OBSTRUCTION OF DIGEST TRACT. IRON OVERDOSE MAY BE FATAL. CHRONIC:INHAL CAN PRDCE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:MOTTLING(SPOTTING) OF LUNGS(SIDEROSIS). THIS CNDTN IS OFTEN W/OUT SYMPS & HAS BEEN REFERRED TO AS "BENIGN (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:RADIOPAQUE PNEUMOCONIOSIS". INGEST OF >50-100 MG OF IRON PER DAY MAY RSLT IN PATHOLOGICAL IRON DEPOSITION (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:IN BODY TISS. SYMPS INCL FIBROSIS (SCARRING) OF PANCREAS, DIABETES MELLITUS & LIVER CIRRHOSIS. RPTD IRON (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:INGEST CAN PRDCE CARDIAC TOX. TARGET ORGANS:EYES, RESPIRATORY TRACT, LIVER & PANCREAS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:GIVE ANYTHING BY MOUTH TO UNCON/CONVULSING PERS. IF INGESTED, HAVE CONSCIOUS & ALERT PERS DRINK (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:1-2 GLASSES OF WATER, THEN INDUCE VOMIT. CONSULT POIS CTL CTR. AFTER FIRST AID, GET APPROP IN-PLANT, (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:PARAMEDIC/COMMUNITY MED SUPPORT. NOTE TO MD:MANAGEMENT OF IRON POIS BY INGEST IS COMPLEX & BEYOND THIS (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:MSDS'S SCOPE. CONSULT A MEDICAL TOXICOLOGIST. RTECS #:9999999ZZ Ingred Name:SPILL PROC:CARE DURING CLEANUP. FOR LG SPILLS, FLUSH MATL W/STREAM OF WATER & DIKE FOR LATER DISP. FOLLOW APPLIC(ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:OSHA REGULATIONS (29 CFR 1910.120). RTECS #:9999999ZZ Ingred Name:OTHER PREC:OPERATIONS OF MACHINERY IS ADVISABLE WHEN AT ALL POSSIBLE. RTECS #:9999999ZZ Ingred Name:VENT:PREVENTS CONTAMINANT DISPERSION INTO WORK AREA BY CONTROLLING IT AT ITS SOURCE. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:DRENCH SHOWERS & WASHING FACILITIES. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT:AREAS. PRACTICE GOOD PERSONAL HYGIENE AFTER USING THIS MATL, ESP BEFORE EATING, DRINKING, SMOKING,(ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:USING TOILET/APPLYING COSMETICS. SINCE CONTACT LENS USE IN INDUSTRY IS CONTROVERSIAL, ESTABLISH YOUR OWN POLICY. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL MAY BE IRRIT TO RESP TRACT. EYE CONT MAY CAUSE CONJ (INFLAMM OF EYE'S LINING) & DEPOSITION OF IRON PARTICLES CAN LEAVE "RUST RING"/BROWNISH STAIN ON CORNEA. IRON'S ACUTE TOX RSLTS PRIMARIL Y FROM ACCIDENTAL/SUICIDAL INGESTS (E.G., OVERDOSE OF IRON-CNTNG VITAMIN PILLS). INITIALLY, PATIENT MAY(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:IMPROVE, BUT SHOULD BE OBSERVED CAREFULLY, AS TOX MAY PROGRESS TO DEVEL OF PROFOUND SHOCK, SEV ACIDOSIS (INCR ACIDITY IN BLOOD), CYANOSIS (BLUISH SKIN DISCOLORATION) & FEVER. TWO TO FOUR DAYS AFTER EXPOS, LIVER DMG MAY OCCUR. W/INSEVERAL WEEKS AFTER EXPOS, IN SEVERAL RARE CASES, GI FIBROSIS (SCARRING) (ING 8) Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY DISEASES. ======================= First Aid Measures ======================= First Aid:EYES:GENTLY LIFT EYELIDS & FLUSH IMMED & CONTINUOUSLY W/FLOODING AMTS OF WATER UNTIL TRANSPORTED TO EMER MED FACILITY (AT LST 15 MINS). CONSULT MD IMMED. SKIN:QUICKLY REMOVE CONTAM CLTHG. RINSE W/FLOO DING AMTS OF WATER FOR AT LST 15 MINS. FOR REDDENED/BLISTERED SKIN, CONSULT MD. WASH AFFECTED AREA W/SOAP & WATER. INHAL:REMOVE EXPOS PERS TO FRESH AIR & SUPPORT BRTHG AS NEEDED. INGEST:NEVER (ING 13) ===================== Fire Fighting Measures ===================== Flash Point:NONE REPORTED Lower Limits:NONE RPTD Upper Limits:NONE RPTD Extinguishing Media:FOR SMALL FIRE, USE WATER SPRAY, CARBON DIOXIDE (CO*2) OR REGULAR FOAM. FOR LG FIRES, USE WATER SPRAY/REGULAR FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . APPLY COOLING WATER SPRAY TO FIRE-EXPOS CNTNR SIDES UNTIL FIRE IS WELL OUT. IF POSS W/NO RISK, (SUPP DATA) Unusual Fire/Explosion Hazard:SINCE FINELY DIVIDED IRON PWDR IS PYROPHORIC & IGNITES UPON EXPOS TO AIR AT NORMAL TEMPS, FIRES & DUST EXPLOS CAN OCCUR IN DUCTS/SEPARATORS USED TO (ING 3) ================== Accidental Release Measures ================== Spill Release Procedures:NOTIFY SFTY PERS. ISOLATE HAZ AREA, DENY ENTRY & STAY UPWIND. SHUT OFF ALL IGNIT SOURCES-NO FLARES, SMOKING/FLAMES IN HAZ AREAS. AVOID DUST GENERATION BY CLEANING SM SPILLS W/DAMP MOP. SINCE FINELY DI VIDED IRON PWDR IS EXPLO, TAKE SPECIAL (ING 17) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID PHYSICAL DMG TO CNTNRS. STORE IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM FLAMM GASES/LIQS, OXIDIZING MATLS/ORG PEROXIDES. AVOID DUST INHAL. Other Precautions:INSTITUTE RESP PROT PROGRAM THAT INCLS REGULAR TRAINING, MAINT, INSPECTION & EVAL. REGULARLY SERVICE DUCTING AT GRINDING & POLISHING MACHINES & FINISHING BELTS TO MAINTAIN EFFICIENCY OF EXHST VENT & P VNT EXPLO. REMOTE CONTROL (ING 19) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SEEK PROFESSIONAL ADVICE PRIOR TO RESPIRATOR SELECTION & USE. FOLLOW OSHA RESPIRATOR REGULATIONS (29 CFR 1910.134) &, IF NECESSARY, WEAR A NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:PROVIDE GEN & LOC EXHST VENT SYS TO MAINTAIN AIRBORNE CONCS BELOW OSHA PEL. LOC EXHST VENT IS PREF SINCE IT (ING 20) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:CHEMICAL SAFETY GOGGLES & FACE SHIELD. Other Protective Equipment:WEAR BOOTS, APRONS & GAUNTLETS TO PVNT ANY SKIN CONT. MAKE AVAIL IN WORK AREA EMER EYEWASH STATIONS, SFTY/QUICK-(ING 21) Work Hygienic Practices:REMOVE THIS MATL FROM YOUR SHOES & EQUIP. LAUNDER CONTAM CLTHG BEFORE WEARING. NEVER EAT, DRINK/SMOKE IN WORK (ING 22) Supplemental Safety and Health APPEAR/ODOR:ROLLED, HAMMERED/BENT), SLIGHTLY MAGNETIC (BECOMING MORE SO AS IT IS ALLOYED; FOR EX, STEEL) METAL. IT IS AVAIL AS INGOTS, WIRE, SHEETS/PWDR. PWDR FORM IS BLACK-GRAY. FIRE FIGHT PROC:REMOV E CNTNRS FROM AREA. FIGHT FIRE FROM AS FAR DIST AS POSS. BE AWARE OF RUNOFF FROM FIRE CONTROL METHS. DO NOT RELS (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:4982F,2750C Melt/Freeze Pt:M.P/F.P Text:2795F,1535C Vapor Pres:1 @ 3248F Spec Gravity:7.86 Solubility in Water:INSOLUBLE Appearance and Odor:PURE, SOLID IRON IS SILVERY-WHITE/GRAY, SOFT, DUCTILE, MALLEABLE (CAN BE(SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SOLID/PWDRD IRON IGNITES/EXPLODES ON CONT W/ACETALDEHYDE, AMMONIUM PEROXODISULFATE, CHLOROFORMAMIDINIUM, CHLORIC (ING 5) Stability Condition to Avoid:READILY OXIDIZES IN MOIST AIR TO FORM RUST. HIGHLY DIVIDED PWDR FORMS ARE VERY UNSTABLE & CAN IGNITE SPONT IN (ING 4) Hazardous Decomposition Products:THERMAL OXIDATIVE DECOMPOSITION OF IRON CAN PRODUCE TOXIC IRON OXIDE FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR SUPPLIER OR A LICENSED CONTRACTOR FOR DETAILED RECOMMENDATIONS. FOLLOW APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS. 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