MALLINKRODT CHEMICAL INC -- STANNOUS CHLORIDE -- 6810-00N065741 
=====================  Product Identification  =====================

Product ID:STANNOUS CHLORIDE
MSDS Date:04/06/1989
FSC:6810
NIIN:00N065741
=== Responsible Party ===
Company Name:MALLINKRODT CHEMICAL INC
Box:800
City:PARIS
State:KY
ZIP:10362
Country:US
Info Phone Num:314-539-1600
Emergency Phone Num:314-539-1600
CAGE:JO201
=== Contractor Identification ===
Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:908-859-2151
CAGE:62910
Company Name:MALLINKRODT CHEMICAL INC
Box:800
City:PARIS
State:KY
ZIP:10362
Country:US
Phone:314-539-1600
CAGE:JO201

=============  Composition/Information on Ingredients  =============

Ingred Name:TIN (II) CHLORIDE DIHYDRATE (1:2:2); (STANNOUS (TIN II)
    CHLORIDE DIHYDRATE)
CAS:10025-69-1
RTECS #:XP8850000
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:TIN (II) CHLORIDE (1:2); (STANNOUS CHLORIDE, SOLID)
CAS:7772-99-8
RTECS #:XP8700000
OSHA PEL:2 MG SN/M3
ACGIH TLV:2 MG SN/M3

Ingred Name:FIRST AID PROC:OR PERSISTS. EYE:WASH W/PLENTY OF WATER FOR
    @ LEAST 15 MINS, LIFTING LOWER & UPPER EYELIDS (ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3:OCCASNLY. GET MED ATTN IMMED.
RTECS #:9999999ZZ

Ingred Name:SPILL RELEASE:RECLAMATION MAY BE DELIVERED TO AN APPRVD
    WASTE DISPOSAL FACILITY.
RTECS #:9999999ZZ

Ingred Name:VENT:GENERALLY PREFERRED BECAUSE IT CAN CONTROL EMISSIONS
    OF THE CONTAMINANT AT ITS SOURCE, PVNTG DISPERSION (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:OF IT INTO THE GENERAL WORK AREA. PLEASE REFER TO
    ACGIH DOCUMENT, "INDUST VENT, A MANUAL OF REC PRACTICES",(ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:MOST RECENT EDITION, FOR DETAILS.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50:(ORAL,RAT) 700 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:INHAL OF DUST MAY CAUSE
    IRRIT & DMG TO RESP TRACT & MUC MEMB. SYMPS MAY INCL SORE THROAT,
    COUGHING, & LABORED BRTHG. INGEST:MAY CAUSE BURNING IN MOUTH &
    THROAT, VOMIT, ABDOM PAIN, DIARR, R EDUCED BLOOD PRESS, STOM
    BLEEDING, COLLAPSE & CONVL. MAY CAUSE LIVER & KIDNEY DMG. SKIN:MAY
    CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:IRRIT, REDNESS & PAIN. EYE:MAY CAUSE
    IRRIT, REDNESS & PAIN. CHRONIC:RPTD SKIN CONT W/SOLN MAY CAUSE SKIN
    RASHES IN SUSCEPTIBLE INDIVIDUALS. PRLNGD INHAL OF DUST/FUME MAY
    RSLT IN BENIGN PNEUMO CONIOSIS, PRODUCING DISTINCTIVE CHANGESIN
    LUNGS W/NO APPARENT DISABILITY OR COMPLICATIONS.
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
    DISORDERS OR EYE PROBLEMS, OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
    FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
    BRTHG IS DFCLT, GIVE OXYG. CALL PHYS. INGEST:INDUCE VOMIT IMMED BY
    GIVING 2 GLASSES OF WATER/MILK IF AVAIL & STICKING FINGER DOWN
    THROAT. CA LL PHYS IMMED. NEVER GIVE ANYTHING BY MOUTH TO UNCON
    PERSON. SKIN:REMOVE ANY CONTAMD CLTHG. WIPE OFF EXCESS FROM SKIN.
    WASH W/SOAP & WATER FOR @ LEAST 15 MINS. GET MED ATTN IF IRRIT
    DEVELOPS (ING 3)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
    SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED AN EXPLO HAZ, BUT REACTS
    EXPLOSIVELY WHEN MIXED W/NITRATES/HYDROGEN PEROXIDE (>3% SOLUTION).

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. CLEAN-UP PERS
    MAY REQ RESP PROT FROM DUST. SPILLS:SWEEP UP & CONTAINERIZE IN
    CORR-RESIST CNTNR FOR RECLAMATION/DISP. VACUUMING/WET SWEEPING MAY
    BE USED TO AVOID DUST DISP ERSAL. WHATEVER CANNOT BE SAVED FOR (ING
    5)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR, STORED IN
    COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE.
    ISOLATE FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:AQUEOUS SOLUTIONS ARE ACIDIC; USE ONLY IN
    CORROSION-RESISTANT VESSELS. CONTACT LENSES SHOULD BE WORN WHEN
    WORKING W/THIS MATL. AVOID BRTHG DUST. KEEP CNTNR CLSD. USE W/ADEQ
    VENT. AVOID CONT W/EYES.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF TLV IS EXCEEDED, NIOSH/MSHA APPRVD DUST/MIST
    RESP W/CHEM GOGG MAY BE WORN, IN GEN, UP TO TEN TIMES TLV. CONSULT
    RESP SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, NIOSH/MSHA APPRVD
    SUPPLIED AIR FULL FAC EPIECE RESP/AIRLINED HOOD MAY BE WORN.
Ventilation:A SYS OF LOC AND/OR GEN EXHAUST IS REC TO KEEP EMPLOYEE
    EXPOS BELOW AIRBORNE EXPOS LIM. LOC EXHAUST VENT IS (ING 6)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
    SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SOL IN H*2O:118G/100ML WATER @ 0C (32F). CNDTNS TO AVOID:FORMS THE
    INSOLUBLE OXYCHLORIDE. FORMS AN INSOLUBLE BASIC SALT WHEN DISSOLVED
    W/MUCH WATER. MATLS TO AVOID:W/HYDRAZINE HYDRATE TO FORM DIHYDRAZ
    INE CHLORIDE, WHICH DECOMPOSES EXPLO WHEN HEATED. CONT W/STRONG
    OXIDIZING AGENTS/ALKALIS WILL GENERATE HEAT & FUMES.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:100F,38C
Spec Gravity:2.71
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:SUPP DATA
Appearance and Odor:COLORLESS CRYSTALS, SLIGHT ODOR OF HYDROCHLORIC
    ACID.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
SODIUM, POTASSIUM, BROMINE TRIFLUROIDE, CALCIUM CARBIDE, CALCIUM
    ACETYLIDE, ETHYLENE OXIDE, & NITRATES. REACTS (SUPDAT)
Stability Condition to Avoid:POWERFUL REDUCING AGENT. SM QTYS OF
    HYDROCHLORIC ACID ARE PRESENT IN AQUEOUS SOLN. ABSORBS OXYG FROM
    AIR & (SUPDAT)
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION IT EMITS
    TOXIC AND CORROSIVE FUME OF HYDROCHLORIC ACID.

====================  Disposal Considerations  ====================

Waste Disposal Methods:ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL
    REGULATIONS.

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 of Defense.  The United States of America in no manner whatsoever,
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